This paper proposes a kind of method of three-phase voltage phase locked loop under three-phase unbalanced voltage. When the positive dq synchronous reference frame transforms, the dq axis voltage component will contain AC component caused by negative sequence voltage component which leads to the error of the three-phase voltage phase locked loop (PLL) based on the dq synchronous reference frame transformation. After the dq axis DC voltage component extracted from negative sequence dq synchronous reference frame transformation compensates positive sequence dq transformation synchronous reference frame q axis voltage component, the positive sequence voltage phase can be locked accurately and quickly. By the way of the negative sequence dq synchronous reference frame d axis and q axis DC voltage component detecting negative sequence voltage initial phase angle, the negative sequence voltage phase can be locked. The simulation results show that, this method can achieve the purpose that three-phase power supply frequency, positive sequence voltage phase and the negative sequence voltage phase can be fast and accurately locked in case of unbalanced three-phase voltage.